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|Title: ||Chemical Interactions at Metal/Molecule Interfaces in Molecular Junctions-A Pathway Towards Molecular Recognition|
|Authors: ||Manolova, Milo|
Kolb, Dieter M.
|Issue Date: ||2009|
|Publisher: ||WILEY-V C H VERLAG GMBH|
|Citation: ||ADVANCED MATERIALS, 21(3). p. 320-324|
|Abstract: ||A 4-aminothiophenol self-assembled monolayer (see image) is prepared on top of a Au(111) crystal, which is subsequently metallized by a nearly closed Pd overlayer of monoatomic height. Analysis of its structural setup and electronic properties reveals that the monolayer consists of a minimum of two molecular layers, and strong chemical interactions between the metal overlayer and the amino groups are found to play a decisive role in determining the overall electronic, and thus the transport properties, of the layer/metal contact.|
|Notes: ||[Boyen, Hans-Gerd] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Manolova, Milo; Ivanova, Valentina; Kolb, Dieter M.] Univ Ulm, Inst Electrochem, D-89069 Ulm, Germany. [Kucera, Jan; Gross, Axel] Univ Ulm, Inst Theoret Chem, D-89069 Ulm, Germany. [Romanyuk, Andriy; Oelhafen, Peter] Univ Basel, Inst Phys, CH-4056 Basel, Switzerland.|
|ISI #: ||000263081700007|
|Type: ||Journal Contribution|
|Validation: ||ecoom, 2010|
|Appears in Collections: ||Research publications|
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