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Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3889

Title: A SOLID-STATE NMR INVESTIGATION OF THE DOPABILITY OF POLY(P-PHENYLENE VINYLENE) MODEL COMPOUNDS AND CORRESPONDING POLYMERS WITH IODINE
Authors: NOUWEN, J
ADRIAENSENS, Peter
FRANCO, Dirk
VANDERZANDE, Dirk
MARTENS, Harry
GELAN, Jan
YANG, Z
GEISE, HJ
Issue Date: 1992
Publisher: ELSEVIER SCIENCE SA LAUSANNE
Citation: SYNTHETIC METALS, 48(2). p. 143-159
Abstract: Twelve phenylene vinylene compounds, including poly(p-phenylene vinylene) (PPV), poly(2,5-dimethoxyphenylene vinylene) and the copolymer of PPV and poly(2,5-dimethoxyphenylene vinylene), have been prepared and doped with iodine to form electrically conducting materials. Characterization of the molecular structure and conductivity as a function of the dopant level for trans,trans-1,4-bis(2-(3,4,5-trimethoxyphenyl)ethenyl)benzene (MPV4) and trans-3,4,4',5-tetramethoxystilbene (MPV7) were carried out. Methoxy groups in a para position on the terminal rings contribute more to the conductivity than meta-substituted methoxy groups. This correlates well with the spectral changes that occur in the CP/MAS C-13 spectra upon doping. Conductivity measurements on trans-stilbene (MPV8), trans, trans-distyrylbenzene (MPV9) and all-trans PPV show a slight chain length dependency. Upon doping with iodine, cis-trans mixtures of MPV4 are converted to trans, trans isomers, and the original double bond configuration does not affect the conductivity.
Notes: UNIV INSTELLING ANTWERP,DEPT CHEM,B-2610 WILRIJK,BELGIUM.NOUWEN, J, UNIV LIMBURG,INST MAT RES,UNIV CAMPUS,B-3590 DIEPENBEEK,BELGIUM.
URI: http://hdl.handle.net/1942/3889
DOI: 10.1016/0379-6779(92)90057-P
ISI #: A1992JB15000002
ISSN: 0379-6779
Type: Journal Contribution
Appears in Collections: Research publications

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