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Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3791

Title: AG(I)-N-METHYLSUBSTITUTED 1,3-DIAMINOPROPANE COMPLEXES IN 1-M NO3-
Authors: GARNER, R
YPERMAN, Jan
MULLENS, Jules
VAN POUCKE, Lucien
Issue Date: 1994
Publisher: GORDON BREACH SCI PUBL LTD
Citation: JOURNAL OF COORDINATION CHEMISTRY, 31(2). p. 117-123
Abstract: The complexation behaviour of a number of N-methylpropylene diamines with Ag(I) were studied in 1 M KNO3 at 25.00-degrees-C potentiometrically, employing pH and pAg measurements. Several metal/ligand ratios were used (varying from 2/1 to 1/8). Complexation of these ligands with Ag(I) in aqueous solution is described by the following species: AgL, AgLH, AgL2, AgL2H, AgL2H2, Ag2L2 and Ag2L2H. No mixed ligand hydroxo species could be detected in the concentration employed. Stability constants of a given species systematically decrease as methylation increases on the terminal amino groups due to increased steric effects.
Notes: LIMBURGS UNIV CENTRUM,INORGAN & PHYS CHEM LAB,B-3590 DIEPENBEEK,BELGIUM.
URI: http://hdl.handle.net/1942/3791
ISI #: A1994NM52600004
ISSN: 0095-8972
Type: Journal Contribution
Appears in Collections: Research publications

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