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Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3771

Title: MISCIBILITY OF POLY(PARA-PHENYLENE VINYLENE) MODEL COMPOUNDS WITH POLYCARBONATE STUDIED BY SOLID-STATE NMR
Authors: NOUWEN, J
PAULUSSEN, Harald
VERREYT, G
YANG, Z
GEISE, HJ
ADRIAENSENS, Peter
VANDERZANDE, Dirk
GELAN, Jan
Issue Date: 1993
Publisher: ELSEVIER SCIENCE SA LAUSANNE
Citation: SYNTHETIC METALS, 59(2). p. 171-179
Abstract: Wittig synthesis of 2,5-dimethoxy-1,4-bis(2-(3,4,5-trimethoxyphenyl)ethenyl)benzene (MPV) was shown by high-temperature GC/MS to consist of about 34% cis,cis-, 46% trans, cis- and 20% trans, trans-configurations. The configurational mixture blended with polycarbonate (PC) results in homogeneous, intimate mixing at the molecular level for all investigated weight ratios MPV/PC (up to 60/40%). This follows from (i) the occurrence of cross-peaks in two-dimensional H-1 combined rotation and multiple pulse NMR spectroscopy (CRAMPS), and (ii) the observation of one common proton spin-locking relaxation time (T1rhoH) for all protons in the mixture together with a linear variation of these T1rhoH values as a function of the mixture composition.
Notes: UNIV INSTELLING ANTWERP,UIA,DEPT CHEM,B-2610 WILRIJK,BELGIUM.NOUWEN, J, UNIV LIMBURG,INST MAT RES,DIV CHEM,UNIV CAMPUS,B-3590 DIEPENBEEK,BELGIUM.
URI: http://hdl.handle.net/1942/3771
ISI #: A1993LJ80400004
ISSN: 0379-6779
Type: Journal Contribution
Appears in Collections: Research publications

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