www.uhasselt.be
DSpace

Document Server@UHasselt >
Research >
Research publications >

Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3645

Title: A POTENTIOMETRIC STUDY OF THE COMPLEXATION OF ALIPHATIC ACYCLIC MONOAMINES WITH AG(I) IN 1 M NITRATE
Authors: GARNER, R
YPERMAN, Jan
MULLENS, Jules
VAN POUCKE, Lucien
Issue Date: 1993
Publisher: GORDON BREACH SCI PUBL LTD
Citation: JOURNAL OF COORDINATION CHEMISTRY, 30(2). p. 151-164
Abstract: Complexation of 12 aliphatic monoamines with Ag(I) has been studied in IM KNO3 at 25-degrees-C using a potentiometric titration technique, performing pH and pAg measurements. To study these ternary systems, the binary systems (Ag-OH, LH, H-OH) were first investigated. The model used for background Ag(I) hydrolysis is consistent with the literature. Graphical techniques were used for the calculation of formation constants of silver-amine complexes. The estimates were further refined using the Superquad program. Evidence has been found for the formation of mixed Ag(I)-hydroxo ligand complexes only with aliphatic primary monoamines.
Notes: LIMBURGS UNIV CENTRUM,INORGAN & PHYS CHEM LAB,B-3590 DIEPENBEEK,BELGIUM.
URI: http://hdl.handle.net/1942/3645
ISI #: A1993MP03500006
ISSN: 0095-8972
Type: Journal Contribution
Appears in Collections: Research publications

Files in This Item:

There are no files associated with this item.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.