www.uhasselt.be
DSpace

Document Server@UHasselt >
Research >
Research publications >

Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3486

Title: Unexpected rearrangements in the synthesis of arylidene- or alkylidene-2-thiophthalides
Authors: PAULUSSEN, Harald
ADRIAENSENS, Peter
VANDERZANDE, Dirk
GELAN, Jan
Issue Date: 1996
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Citation: TETRAHEDRON, 52(36). p. 11867-11878
Abstract: Mechanistic studies concerning the reaction by which poly(isothianaphthene) (PITN) is synthesized in one step from commercially available monomers by reacting them with phosphorus pentasulphide (P4S10), have led to the idea of synthesizing a chain-stopper molecule which should give rise to suitable quinoid model compounds For PITN. Within this context benzylidenedithiophthalide and pentylidenedithiophthalide were chosen as target molecules. The unexpected rearrangements and the control of there rearrangements in the synthesis of benzylidenedithiophthalide and pentylidenedithiophthalide are reported. Copyright (C) 1996 Elsevier Science Ltd.
Notes: UNIV LIMBURG,INST MAT RES,DIV CHEM,B-3590 DIEPENBEEK,BELGIUM.
URI: http://hdl.handle.net/1942/3486
DOI: 10.1016/0040-4020(96)00678-3
ISI #: A1996VE83000017
ISSN: 0040-4020
Type: Journal Contribution
Appears in Collections: Research publications

Files in This Item:

There are no files associated with this item.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.