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Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3305

Title: Transient effects can change identifiability criteria for complex excited-state processes
Authors: Molski, A
Boens, N
AMELOOT, Marcel
Issue Date: 1997
Publisher: ELSEVIER SCIENCE BV
Citation: CHEMICAL PHYSICS LETTERS, 266(1-2). p. 139-144
Abstract: The identifiability of two-state excited-state processes is studied when transient effects are present. When the emission bands of the excited species are well separated, the deactivation rate constants of the two excited species to their respective ground states, k(01) and k(02), can be determined from two decay traces of the individual excited species at one concentration. Thus, two decay traces are sufficient for the recovery of k(01) and k(02) for inter- and intra-molecular two-state excited-state processes. When transient effects are absent more kinetic information is needed for the recovery of k(01) and k(02).
Notes: KATHOLIEKE UNIV LEUVEN,DEPT CHEM,B-3001 HEVERLEE,BELGIUM. LIMBURGS UNIV CTR,B-3590 DIEPENBEEK,BELGIUM.
URI: http://hdl.handle.net/1942/3305
DOI: 10.1016/S0009-2614(96)01523-0
ISI #: A1997WJ27600022
ISSN: 0009-2614
Type: Journal Contribution
Appears in Collections: Research publications

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