www.uhasselt.be
DSpace

Document Server@UHasselt >
Research >
Research publications >

Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3190

Title: Polymerization mechanism of 1-[(butylsulfi(o)nyl)metyl]-4-(halomethyl)benezene: The effect of polarizer and leaving group
Authors: Issaris, A
VANDERZANDE, Dirk
ADRIAENSENS, Peter
GELAN, Jan
Issue Date: 1998
Publisher: AMER CHEMICAL SOC
Citation: MACROMOLECULES, 31(14). p. 4426-4431
Abstract: A synthesis route to soluble high molecular weight poly(p-xylylene) derivatives has been investigated. This method provides a versatile route to poly(phenylenevinylene) (PPV) from a precursor polymer that is amenable to the conventional nonaqueous processing techniques. To investigate the mechanism in the solvent mixture, monomethylformamide (MMF)/CH2Cl2 (60/40), the influence of the leaving group and polarizer of the monomer was studied. The evaluation of the molecular weight of the polymer, the polymer yield, and the residual low molecular weight fraction indicates that only the kind of polarizer has an effect on the reaction in contrast with the leaving group, having no observable effect.
Notes: Limburgs Univ Ctr, Inst Mat Res, Lab Organ & Polymer Chem, Div Chem, B-3590 Diepenbeek, Belgium.Vanderzande, D, Limburgs Univ Ctr, Inst Mat Res, Lab Organ & Polymer Chem, Div Chem, Univ Campus, B-3590 Diepenbeek, Belgium.
URI: http://hdl.handle.net/1942/3190
ISI #: 000074853700004
ISSN: 0024-9297
Type: Journal Contribution
Validation: ecoom, 1999
Appears in Collections: Research publications

Files in This Item:

There are no files associated with this item.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.