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Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3149

Title: A highly efficient route towards well-defined modifications of poly(p-phenylene vinylene)
Authors: de Kok, MM
van Breemen, AJJM
ADRIAENSENS, Peter
van Dixhoorn, A
GELAN, Jan
VANDERZANDE, Dirk
Issue Date: 1998
Publisher: WILEY-V C H VERLAG GMBH
Citation: ACTA POLYMERICA, 49(9). p. 510-513
Abstract: The microstructure of PPV is very efficiently modified by partial oxidation of the sulfinyl precursor polymer towards PPV. Controlled oxidation leads to a copolymer with sulfinyl and sulfonyl groups. The sulfinyl groups can be eliminated selectively yielding PPV with restricted conjugation lengths. The optical properties of the obtained conjugated polymers change linearly with the amount in introduced sp(3) defects while the efficiencies of photoluminescence rise also linearly and considerably.
Notes: Univ Limburg, Inst Mat Res, Div Chem, Lab Organ & Polymer Chem, B-3590 Diepenbeek, Belgium.de Kok, MM, Univ Limburg, Inst Mat Res, Div Chem, Lab Organ & Polymer Chem, B-3590 Diepenbeek, Belgium.dvanderz@luc.ac.be
URI: http://hdl.handle.net/1942/3149
Link to publication: http://doi.wiley.com/10.1002/(SICI)1521-4044(199809)49:9%3C510::AID-APOL510%3E3.0.CO;2-9
ISI #: 000076443300009
ISSN: 0323-7648
Type: Journal Contribution
Validation: ecoom, 1999
Appears in Collections: Research publications

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