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Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/2899

Title: Scope and limitations of a new highly selective synthesis of unsymmetrical monomers for the synthesis of precursors toward poly(arylenevinylene)s
Authors: Van der Borght, M
VANDERZANDE, Dirk
ADRIAENSENS, Peter
GELAN, Jan
Issue Date: 2000
Publisher: AMER CHEMICAL SOC
Citation: JOURNAL OF ORGANIC CHEMISTRY, 65(2). p. 284-289
Abstract: In our laboratory a precursor route to poly(p-phenylenevinylene) derivatives is developed in which unsymmetrically substituted p-xylene derivatives, possessing a benzylic sulfinylalkyl group, are used as monomers. Because of this unsymmetry, we were forced to investigate thoroughly the synthesis of these sulfoxides, as we start from symmetric and readily accessible molecules, namely, bis(halomethyl)-p-xylene derivatives. In a former publication, a new extremely effective route for the production of these unsymmetrically substituted sulfinyl monomers was presented. This paper expands upon these previously reported results. To examine the scope and limitations of this elegant route, this new method was applied to the synthesis of various derivatives not included in the initial work.
Notes: Univ Limburg, Inst Mat Res, Div Chem, Lab Organ & Polymer Chem, B-3590 Diepenbeek, Belgium.Vanderzande, D, Univ Limburg, Inst Mat Res, Div Chem, Lab Organ & Polymer Chem, Univ Campus, B-3590 Diepenbeek, Belgium.
URI: http://hdl.handle.net/1942/2899
ISI #: 000084905400002
ISSN: 0022-3263
Category: A1
Type: Journal Contribution
Validation: ecoom, 2001
Appears in Collections: Research publications

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