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Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/21624

Title: Controlled/living polymerization towards functional poly(p-phenylene vinylene) materials
Authors: Zaquen, Neomy
Lutsen, Laurence
Vanderzande, Dirk
Junkers, Thomas
Issue Date: 2016
Publisher: ROYAL SOC CHEMISTRY
Citation: Polymer Chemistry, 7 (7), p. 1355-1367
Abstract: Poly(p-phenylene vinylene)s (PPVs) are an important class of highly fluorescent polymeric semiconductor materials. Despite their somewhat declining use in optoelectronic applications, PPV synthesis routes were in recent years significantly improved towards controlled/living polymerization. In this way, nowadays well-defined PPV structures that can be implemented in advanced polymer structures have become accessible, finding a potential application in new fields of research. This review summarizes the advances made and the types of polymers that have recently become available. Most notably, two polymerization approaches are compared, living polymerization towards well-defined PPVs via ring-opening metathesis polymerization (ROMP) and chain-transfer radical and anionic polymerization in the so-called sulfinyl precursor polymerization route.
Notes: [Zaquen, N.; Junkers, T.] Hasselt Univ, Inst Mat Res IMO, Polymer React Design PRD Grp, Martelarenlaan 42, B-3500 Hasselt, Belgium. [Lutsen, L.; Vanderzande, D.; Junkers, T.] IMEC Associated Lab IMOMEC, Wetenschapspk 1, B-3590 Diepenbeek, Belgium. [Lutsen, L.; Vanderzande, D.] Hasselt Univ, Design & Synth Organ Semicond Grp, Inst Mat Res IMO, Martelarenlaan 42, B-3500 Hasselt, Belgium.
URI: http://hdl.handle.net/1942/21624
DOI: 10.1039/c5py01987g
ISI #: 000369692700001
ISSN: 1759-9954
Category: A1
Type: Journal Contribution
Validation: ecoom, 2017
Appears in Collections: Research publications

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