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Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/20688

Title: Improved Livingness and Control over Branching in RAFT Polymerization of Acrylates: Could Microflow Synthesis Make the Difference?
Authors: Derboven, Pieter
Van Steenberge, Paul H. M.
Vandenbergh, Joke
Reyniers, Marie-Francoise
Junkers, Thomas
D'hooge, Dagmar R.
Marin, Guy B.
Issue Date: 2015
Publisher: WILEY-V C H VERLAG GMBH
Citation: MACROMOLECULAR RAPID COMMUNICATIONS, 36 (24), p. 2149-2155
Abstract: The superior capabilities of structured microreactors over batch reactors are demonstrated for reversible addition-fragmentation chain transfer (RAFT) solution polymerization of n-butyl acrylate with the aid of simulations, explicitly accounting for the chain length distribution of all macrospecies types. Since perfect isothermicity can be established in a microreactor, less side products due to backbiting and beta-scission are formed compared to the batch operation in which ineffective heat removal leads to an undesirable temperature spike. For a given RAFT chain transfer agent (CTA), additional microstructural control results under microflow conditions by optimizing the reaction temperature, lowering the dilution degree, or decreasing the initial molar ratio of monomer to RAFT CTA.
Notes: [Derboven, Pieter; Van Steenberge, Paul H. M.; Reyniers, Marie-Francoise; D'hooge, Dagmar R.; Marin, Guy B.] Univ Ghent, Chem Technol Lab, B-9052 Zwijnaarde, Ghent, Belgium. [Vandenbergh, Joke; Junkers, Thomas] Univ Hasselt, Inst Mat Res IMO Imomec, Polymer React Design Grp, B-3590 Diepenbeek, Belgium. [D'hooge, Dagmar R.] Univ Ghent, Dept Text, B-9052 Zwijnaarde, Ghent, Belgium.
URI: http://hdl.handle.net/1942/20688
DOI: 10.1002/marc.201500357
ISI #: 000368033500005
ISSN: 1022-1336
Category: A1
Type: Journal Contribution
Validation: ecoom, 2017
Appears in Collections: Research publications

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