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Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/20240

Title: Synthesis, characterization and catalytic activity of novel large network polystyrene-immobilized organic bases
Authors: Tassi, Marco
Adriaensens, Peter
Bianchi, Luca
Barkakaty, Balaka
Carleer, Robert
Chen, Jihua
Hensley, Dale K.
Marrocchi, Assunta
Vaccaro, Luigi
Bartollini, Elena
Issue Date: 2015
Publisher: RSC
Citation: RSC Advances, 5 (130), p. 107200-107208
Series/Report no.: 130
Abstract: In view of searching for efficient polymeric supports for organic bases to be used in environmentally friendly reaction conditions, novel gel-type cross-linked polystyrenes functionalized with diethylamine and 1,5,7-triazabicyclo[4.4.0]dec-5-ene, have been prepared. The structural properties and morphology of these catalysts have been determined by extensive solid state NMR experiments, FTIR spectroscopy and SEM/TEM microscopy. SPACeR-supported bases were found to exhibit high catalytic activity in the epoxide ring opening by phenols. A range of β-substituted alcohols have been readily and regioselectively synthesized.
Notes: Vaccaro, L (reprint author), Univ Perugia, CEMIN Dipartimento Chim Biol & Biotecnol, Lab Green Synthet Organ Chem, Via Elce di Sotto 8, I-06123 Perugia, Italy. luigi.vaccaro@unipg.it
URI: http://hdl.handle.net/1942/20240
DOI: 10.1039/C5RA21140A
ISI #: 000367271700002
ISSN: 2046-2069
Category: A1
Type: Journal Contribution
Validation: ecoom, 2017
Appears in Collections: Research publications

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