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|Title: ||Synthesis, characterization and catalytic activity of novel large network polystyrene-immobilized organic bases|
|Authors: ||Tassi, Marco|
Hensley, Dale K.
|Issue Date: ||2015|
|Citation: ||RSC Advances, 5 (130), p. 107200-107208|
|Series/Report no.: ||130|
|Abstract: ||In view of searching for efficient polymeric supports for organic bases to be used in environmentally friendly reaction conditions, novel gel-type cross-linked polystyrenes functionalized with diethylamine and 1,5,7-triazabicyclo[4.4.0]dec-5-ene, have been prepared. The structural properties and morphology of these catalysts have been determined by extensive solid state NMR experiments, FTIR spectroscopy and SEM/TEM microscopy. SPACeR-supported bases were found to exhibit high catalytic activity in the epoxide ring opening by phenols. A range of β-substituted alcohols have been readily and regioselectively synthesized.|
|Notes: ||Vaccaro, L (reprint author), Univ Perugia, CEMIN Dipartimento Chim Biol & Biotecnol, Lab Green Synthet Organ Chem, Via Elce di Sotto 8, I-06123 Perugia, Italy.
|ISI #: ||000367271700002|
|Type: ||Journal Contribution|
|Validation: ||ecoom, 2017|
|Appears in Collections: ||Research publications|
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|published version||841.13 kB||Adobe PDF|
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