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Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/18850

Title: Molecular orientation of lead phthalocyanine on (100) oriented single crystal diamond surfaces
Authors: DEXTERS, Wim
BOURGEOIS, Emilie
NESLADEK, Milos
D'HAEN, Jan
Goovaerts, Etienne
HAENEN, Ken
Issue Date: 2015
Publisher: ROYAL SOC CHEMISTRY
Citation: PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 17 (15), p. 9619-9623
Abstract: Lead phthalocyanine (PbPc) thin films of 5 and 50 nm have been deposited on hydrogen and oxygen terminated single crystal diamond (SCD) using organic molecular beam deposition. Atomic force microscopy and X-ray diffraction (XRD) studies showed that PbPc grown on the hydrogen terminated SCD forms layers with a high degree of crystallinity, dominated by the monoclinic (320) orientation parallel to the diamond surface. The oxygen terminated diamond led to a randomly oriented PbPc film. Absorption and photocurrent measurements indicated the presence of both polymorphs of PbPc, however, the ratio differed depending on the termination of the SCD. Finally, polarized Raman spectroscopy was used to determine the orientation of the molecules of the thin film. The results confirmed the random orientation on the O-terminated diamond. On SCD:H, the PbPc molecules are lying down in accordance with the XRD results.
Notes: [Dexters, Wim; Bourgeois, Emilie; Nesladek, Milos; D'Haen, Jan; Haenen, Ken] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Bourgeois, Emilie; Nesladek, Milos; D'Haen, Jan; Haenen, Ken] IMEC VZW, IMOMEC, B-3590 Diepenbeek, Belgium. [Goovaerts, Etienne] Univ Antwerp, Dept Phys, B-2610 Antwerp, Belgium.
URI: http://hdl.handle.net/1942/18850
DOI: 10.1039/c5cp00174a
ISI #: 000352270700003
ISSN: 1463-9076
Category: A1
Type: Journal Contribution
Validation: ecoom, 2016
Appears in Collections: Research publications

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