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Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/18675

Title: Quinoxaline-Based Cyclo(oligophenylenes)
Authors: MARIN, Lidia
KUDRJASOVA, Julija
VERSTAPPEN, Pieter
PENXTEN, Huguette
Robeyns, Koen
LUTSEN, Laurence
Vanderzande, Dirk J. M.
MAES, Wouter
Issue Date: 2015
Publisher: AMER CHEMICAL SOC
Citation: JOURNAL OF ORGANIC CHEMISTRY, 80 (4), p. 2425-2430
Abstract: A series of fully conjugated quinoxaline-based oligophenylene macrocycles is synthesized by Ni-0-mediated Yamamoto-type diaryl homocoupling of (fluorinated) 2,3-bis(4'-bromophenyl)quinoxaline precursors. Cyclotrimers and cyclotetramers are obtained as the dominant reaction products. The cyclooligomers are fully characterized, including single-crystal X-ray structures, and their optoelectronic properties are analyzed with respect to possible applications in hostguest chemistry and organic electronics.
Notes: [Marin, Lidia; Kudrjasova, Julija; Verstappen, Pieter; Penxten, Huguette; Lutsen, Laurence; Vanderzande, Dirk J. M.; Maes, Wouter] Hasselt Univ, Inst Mat Res IMO IMOMEC, B-3590 Diepenbeek, Belgium. [Marin, Lidia; Kudrjasova, Julija; Verstappen, Pieter; Penxten, Huguette; Lutsen, Laurence; Vanderzande, Dirk J. M.; Maes, Wouter] IMEC, IMOMEC Ass Lab, B-3590 Diepenbeek, Belgium. [Robeyns, Koen] UCL, IMCN, B-1348 Louvain La Neuve, Belgium.
URI: http://hdl.handle.net/1942/18675
DOI: 10.1021/jo502771a
ISI #: 000349943000041
ISSN: 0022-3263
Category: A1
Type: Journal Contribution
Validation: ecoom, 2016
Appears in Collections: Research publications

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