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|Title: ||Functionalized Dithienylthiazolo[5,4-d]thiazoles For Solution-Processable Organic Field-Effect Transistors|
|Authors: ||Van Mierloo, Sarah|
Van den Brande, Niko
Boyukbayram, Ayse E.
Rodriguez, Silvio D.
Adriaensens, Peter J.
Van Assche, Guy
Vanderzande, Dirk J.
|Issue Date: ||2012|
|Publisher: ||WILEY-V C H VERLAG GMBH|
|Citation: ||CHEMPLUSCHEM, 77 (10), p. 923-930|
|Abstract: ||A series of 5'-aryl-substituted 2,5-bis(3'-hexylthiophen-2'-yl)thiazolo[5,4-d]thiazole derivatives was synthesized and these expanded semiconductors were investigated as active materials for solution-processable organic field-effect transistors. Field-effect mobilities of up to 10-3 cm2?V-1?s-1 were obtained, representing the first reasonable FET behavior for highly soluble thiazolo[5,4-d]thiazole-based small organic compounds suitable for printable electronics. Thermal and electrooptical material properties were studied by thermogravimetric analysis, differential scanning calorimetry, cyclic voltammetry, and UV/Vis spectroscopy. Trends in thermal and optical data were supported by (time-dependent) density functional theory calculations. Additional X-ray diffraction, atomic force microscopy, and scanning electron microscopy studies provided insight in the relationship between the molecular structures, film morphologies, and FET performances. The fibrillar microcrystalline structure observed for the best-performing thienyl-substituted material was linked to the high mobility.|
|Notes: ||[Ruttens, Bart; D'Haen, Jan; Vanderzande, Dirk J.] Hasselt Univ, Inst Mat Res IMO IMOMEC, Elect & Phys Characterizat ELPHYC, B-3590 Diepenbeek, Belgium. [Vasseur, Karolien; Heremans, Paul] IMEC, B-3001 Louvain, Belgium. [Vasseur, Karolien; Heremans, Paul] Katholieke Univ Leuven, Dept Met & Mat Engn, B-3001 Heverlee, Belgium. [Van den Brande, Niko; Van Assche, Guy] Vrije Univ Brussel, Dept Mat & Chem Phys Chem & Polymer Sci, B-1050 Brussels, Belgium. [Boyukbayram, Ayse E.] Karabuk Univ, Dept Chem, TR-78000 Karabuk, Turkey. [Rodriguez, Silvio D.; Botek, Edith; Liegeois, Vincent; Champagne, Benoit] FUNDP, Lab Chim Theor, B-5000 Namur, Belgium. [Rodriguez, Silvio D.] Univ Buenos Aires, Inst Quim Fis Mat, Buenos Aires, DF, Argentina. [Lutsen, Laurence; Vanderzande, Dirk J.] IMEC, IMOMEC Ass Lab, B-3590 Diepenbeek, Belgium. [Maes, Wouter] Katholieke Univ Leuven, Dept Chem Mol Design & Synth, B-3001 Heverlee, Belgium.|
|ISI #: ||000309751300008|
|Type: ||Journal Contribution|
|Validation: ||ecoom, 2013|
|Appears in Collections: ||Research publications|
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