Document Server@UHasselt >
Research >
Research publications >

Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/13035

Title: Odd-numbered oxacalix[n]arenes (n = 5, 7): synthesis and solid-state structures
Authors: Van Rossom, Wim
Robeyns, Koen
Ovaere, Margriet
Van Meervelt, Luc
Dehaen, Wim
Maes, Wouter
Issue Date: 2011
Citation: ORGANIC LETTERS, 13(1), p. 126-129
Abstract: The critical synthetic access to odd-numbered calix[n]arenes has evidently resulted in less attention for these macrocycles, although specific molecular recognition phenomena have been observed for some of them. A straightforward fragment coupling approach has been designed, applying kinetically controlled nucleophilic aromatic substitution reaction conditions, affording odd-numbered oxacalix[n]arenes (n ) 5, 7) selectively in high yields. The solid-state conformational behavior and the oxacalix[n]arene cavity size were explored by single-crystal X-ray diffraction studies.
Notes: Reprint Address: Dehaen, W (reprint author), Katholieke Univ Leuven, Dept Chem, Celestijnenlaan 200F, B-3001 Louvain, Belgium Addresses: 1. Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium E-mail Address: wim.dehaen@chem.kuleuven.be
URI: http://hdl.handle.net/1942/13035
DOI: 10.1021/ol1026969
ISI #: 000285728000033
ISSN: 1523-7060
Category: A1
Type: Journal Contribution
Appears in Collections: Research publications

Files in This Item:

Description SizeFormat
N/A506.16 kBAdobe PDF

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.